Dipotassium hydrogencarbonate fluoride monohydrate

نویسندگان

  • Volker Kahlenberg
  • Timo Schwaier
چکیده

Single crystals of the title compound, K2(HCO3)F·H2O, were obtained as a secondary product after performing flux synthesis experiments aimed at the preparation of potassium rare earth silicates. The basic building unit of the structure is an [(HCO3)(H2O)F](2-) zigzag chain running parallel to [001]. Both types of anions as well as the water mol-ecules reside on mirror planes perpendicular to [010] at y = 0.25 and y = 0.75, respectively. Linkage between the different constituents of the chains is provided by O-H⋯O and O-H⋯F hydrogen bonding. The K(+) cations are located between the chains and are coordinated by two F and five O atoms in form of a distorted monocapped trigonal prism.

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عنوان ژورنال:

دوره 69  شماره 

صفحات  -

تاریخ انتشار 2013